The install should be straight forward, it should guide you through the setup process and install all the drivers you would need to work with USB Serial or Hardware Serial. I use the Mac version found
here, but once you have it installed on either a mac or windows the Serial examples are the same.
Some labview terminology for you:
1. Programs are called VI's
2. "Front Panel" is where you interact with the program:
3. "Block Diagram" is where you do the programing
4. Once installed there are examples for basic Serial communications and setting Serial Breaks, if you select "Help" drop down, then "Find Examples..." this should show up:
Then search for serial. These screen shots are my Mac but should be the same for windows.
5. To run the VI, select the right COM port and just click the Run button, I outlined them in red:
As far as the Serial Break, I haven't used that feature in Labview so Mark would have to upload the vi and any arduino libraries & sketches that has the problem. I can help on this also in a "Mac" environment once he uploads his VI and points us to the Library and sketches.
I can say that just using the USB Serial with the basic labview examples works fine.